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potassium ethyl xanthate : ウィキペディア英語版
potassium ethyl xanthate

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Potassium ethyl xanthate is an organosulfur compound with the chemical formula CH3CH2OCS2K. It is a pale yellow powder that is used in the mining industry for the separation of ores. Unlike the related sodium ethyl xanthate, the potassium salt exists as an anhydrous salt.
==Production and properties==
Xanthate salts are prepared by the action of alcohols on carbon disulfide. The alkoxide is generated in situ from potassium hydroxide:〔This report gives a detailed procedure 〕
:CH3CH2OH + CS2 + KOH → CH3CH2OCS2K + H2O
Potassium ethyl xanthate is a pale yellow powder that is relatively stable at high pH but rapidly hydrolyses at pH <9 at 25 °C. Unlike the sodium derivative, potassium xanthate crystallizes as the anhydrous salt and is nonhygroscopic.

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